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Steroid A-Ring aromatisation of C-Ring substituted 1,4-dien-3-ones.

Harburn, J.J. and Loftus, G.C. and Marples, B.A. (1998) 'Steroid A-Ring aromatisation of C-Ring substituted 1,4-dien-3-ones.', Journal of chemical research., 8 . pp. 424-425.


A number of A-ring steroidal 1,4-dien-3-ones 7, 8, 9 and 10 have been aromatised in zinc/pyridine–water; the products depend upon the position and type of C-ring substituents and provide new evidence in support of a radical anion mechanism.

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Record Created:22 Nov 2012 12:05
Last Modified:22 Nov 2012 12:24

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