An unprecedented cyclometallated platinum(II)complex incorporating a phosphinine co-ligand: synthesis and photoluminescence behaviour

Moussa, J.; Cheminel, T.; Freeman, G.R.; Chamoreau, L.M.; Williams, J.A.G.; Amouri, H.

doi:10.1039/c4dt00589a

An unprecedented cyclometallated platinum(II)complex incorporating a phosphinine co-ligand: synthesis and photoluminescence behaviour

Moussa, J.; Cheminel, T.; Freeman, G.R.; Chamoreau, L.M.; Williams, J.A.G.; Amouri, H.

Authors

J. Moussa

T. Cheminel

G.R. Freeman

L.M. Chamoreau

Professor Gareth Williams j.a.g.williams@durham.ac.uk
Professor

H. Amouri

Abstract

The first luminescent cyclometallated platinum(II) complex bearing phosphinine co-ligands is reported. The long-lived luminescence, which it displays at 77 K, is assigned to a phosphinine-localised triplet excited state on the basis of electrochemical data and TD-DFT calculations.

Citation

Moussa, J., Cheminel, T., Freeman, G., Chamoreau, L., Williams, J., & Amouri, H. (2014). An unprecedented cyclometallated platinum(II)complex incorporating a phosphinine co-ligand: synthesis and photoluminescence behaviour. Dalton Transactions, 43(22), 8162-8165. https://doi.org/10.1039/c4dt00589a

Journal Article Type	Article
Acceptance Date	Mar 14, 2014
Online Publication Date	Mar 14, 2014
Publication Date	Jun 14, 2014
Deposit Date	Jul 1, 2014
Publicly Available Date	Jul 8, 2014
Journal	Dalton Transactions
Print ISSN	1477-9226
Electronic ISSN	1477-9234
Publisher	Royal Society of Chemistry
Peer Reviewed	Peer Reviewed
Volume	43
Issue	22
Pages	8162-8165
DOI	https://doi.org/10.1039/c4dt00589a