Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II)

Tuxworth, Luke; Baiget, Lise; Phanopoulos, Andreas; Metters, Owen J.; Batsanov, Andrei S.; Fox, Mark A.; Howard, Judith A.K.; Dyer, Philip W.

doi:10.1039/c2cc35623f

Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II)

Tuxworth, Luke; Baiget, Lise; Phanopoulos, Andreas; Metters, Owen J.; Batsanov, Andrei S.; Fox, Mark A.; Howard, Judith A.K.; Dyer, Philip W.

Authors

Luke Tuxworth

Lise Baiget

Andreas Phanopoulos

Owen J. Metters

Andrei S. Batsanov

Dr Mark Fox m.a.fox@durham.ac.uk
Assistant Professor

Judith A.K. Howard

Professor Philip Dyer p.w.dyer@durham.ac.uk
Professor

Abstract

N-Diphenylphosphino-7-aza-benzobicyclo[2.2.1]hept-2-ene (2) behaves as a chelating phosphine–alkene ligand for Pd0 and PdII, promoting direct alkyl–alkyl and indirect alkyl–halide reductive elimination reactions due to the stabilisation of the resulting bis(phosphine–alkene)Pd0 complex.

Citation

Tuxworth, L., Baiget, L., Phanopoulos, A., Metters, O. J., Batsanov, A. S., Fox, M. A., …Dyer, P. W. (2012). Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II). Chemical Communications, 48(84), 10413-10415. https://doi.org/10.1039/c2cc35623f

Journal Article Type	Article
Publication Date	Sep 26, 2012
Deposit Date	May 2, 2013
Publicly Available Date	Jul 18, 2014
Journal	Chemical Communications
Print ISSN	1359-7345
Electronic ISSN	1364-548X
Publisher	Royal Society of Chemistry
Peer Reviewed	Peer Reviewed
Volume	48
Issue	84
Pages	10413-10415
DOI	https://doi.org/10.1039/c2cc35623f