Lanthanide Complexes of Azidophenacyl-DO3A as New Synthons for Click Chemistry and the Synthesis of Heterometallic Lanthanide Arrays

Tropiano, M.; Kenwright, A.M.; Faulkner, S.

doi:10.1002/chem.201500188

Lanthanide Complexes of Azidophenacyl-DO3A as New Synthons for Click Chemistry and the Synthesis of Heterometallic Lanthanide Arrays

Tropiano, M.; Kenwright, A.M.; Faulkner, S.

Authors

M. Tropiano

A.M. Kenwright

S. Faulkner

Abstract

Lanthanide complexes of azidophenacyl DO3A are effective substrates for click reactions with ethyne derivatives, giving rise to aryl triazole appended lanthanide complexes, in which the aryl triazole acts as an effective sensitising chromophore for lanthanide luminescence. They also undergo click chemistry with propargylDO3A derivatives, giving rise to heterometallic complexes.

Citation

Tropiano, M., Kenwright, A., & Faulkner, S. (2015). Lanthanide Complexes of Azidophenacyl-DO3A as New Synthons for Click Chemistry and the Synthesis of Heterometallic Lanthanide Arrays. Chemistry - A European Journal, 21(15), 5697-5699. https://doi.org/10.1002/chem.201500188

Journal Article Type	Article
Acceptance Date	Apr 27, 2015
Online Publication Date	Mar 5, 2015
Publication Date	Apr 7, 2015
Deposit Date	Jun 11, 2015
Publicly Available Date	Mar 5, 2016
Journal	Chemistry - A European Journal
Print ISSN	0947-6539
Electronic ISSN	1521-3765
Publisher	Wiley
Peer Reviewed	Peer Reviewed
Volume	21
Issue	15
Pages	5697-5699
DOI	https://doi.org/10.1002/chem.201500188
Keywords	Click reaction, Energy transfer, Heterometallic, Lanthanide, Luminescence.

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Copyright Statement
This is the peer reviewed version of the following article: Tropiano, M., Kenwright, A. M. and Faulkner, S. (2015), Lanthanide Complexes of Azidophenacyl-DO3A as New Synthons for Click Chemistry and the Synthesis of Heterometallic Lanthanide Arrays. Chem. Eur. J., 21(15): 5697-5699, which has been published in final form at http://dx.doi.org/10.1002/chem.201500188. This article may be used for non-commercial purposes in accordance With Wiley-VCH Terms and Conditions for self-archiving.