Synthesis of polyfluorinated terphenyl and styrene derivatives by palladium catalysed C-F bond activation of polyfluoronitroaromatic substrates

Gadsby, J.M.; McPake, C.B.; Murray, C.B.; Sandford, G.

doi:10.1016/j.jfluchem.2015.10.015

Synthesis of polyfluorinated terphenyl and styrene derivatives by palladium catalysed C-F bond activation of polyfluoronitroaromatic substrates

Gadsby, J.M.; McPake, C.B.; Murray, C.B.; Sandford, G.

Authors

J.M. Gadsby

C.B. McPake

C.B. Murray

G. Sandford

Abstract

Short series of polyfluorinated terphenyl and styrene derivatives were synthesised by palladium catalysed carbon–fluorine bond activation processes involving cross coupling reactions of polyfluorinated nitrobenzene and aryl- and vinyl-boron substrates, respectively.

Citation

Gadsby, J., McPake, C., Murray, C., & Sandford, G. (2016). Synthesis of polyfluorinated terphenyl and styrene derivatives by palladium catalysed C-F bond activation of polyfluoronitroaromatic substrates. Journal of Fluorine Chemistry, 181, 51-55. https://doi.org/10.1016/j.jfluchem.2015.10.015

Journal Article Type	Article
Acceptance Date	Oct 29, 2015
Online Publication Date	Nov 10, 2015
Publication Date	Jan 1, 2016
Deposit Date	Nov 30, 2015
Publicly Available Date	Nov 10, 2016
Journal	Journal of Fluorine Chemistry
Print ISSN	0022-1139
Publisher	Elsevier
Peer Reviewed	Peer Reviewed
Volume	181
Pages	51-55
DOI	https://doi.org/10.1016/j.jfluchem.2015.10.015
Keywords	Carbon-fluorine activation, Palladium catalysis, Cross coupling reaction, Perfluoroaromatic, Pentafluoronitrobenzene.

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http://creativecommons.org/licenses/by-nc-nd/4.0/

Copyright Statement
© 2015 This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/