G.M. Roberts
Spectroscopy and dynamics of the 7,7,8,8-tetracyanoquinodimethane radical anion
Roberts, G.M.; Lecointre, J.; Horke, D.A.; Verlet, J.R .R.
Abstract
The photoelectron spectrum of the 7,7,8,8-tetracyanoquinodimethane (TCNQ) radical anion has been measured at 3.1 eV. Additionally, the ultrafast relaxation dynamics of the first excited state (12B3u) of TCNQ− have been studied using time-resolved photoelectron spectroscopy, which reveals that it undergoes internal conversion back to the ground state (2B2g) with an associated lifetime of 650 fs and shows evidence of coherent nuclear motion.
Citation
Roberts, G., Lecointre, J., Horke, D., & Verlet, J. .. (2010). Spectroscopy and dynamics of the 7,7,8,8-tetracyanoquinodimethane radical anion. Physical Chemistry Chemical Physics, 12(23), 6226-6232. https://doi.org/10.1039/c001438a
Journal Article Type | Article |
---|---|
Acceptance Date | Mar 26, 2010 |
Publication Date | Jun 21, 2010 |
Deposit Date | Jan 28, 2016 |
Publicly Available Date | Feb 5, 2016 |
Journal | Physical Chemistry Chemical Physics |
Print ISSN | 1463-9076 |
Electronic ISSN | 1463-9084 |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 12 |
Issue | 23 |
Pages | 6226-6232 |
DOI | https://doi.org/10.1039/c001438a |
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