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Tethered N-heterocyclic carbene–carboranes : unique ligands that exhibit unprecedented and versatile coordination modes at rhodium.

Holmes, J. and Pask, C.M. and Fox, M.A. and Willans, C.E. (2016) 'Tethered N-heterocyclic carbene–carboranes : unique ligands that exhibit unprecedented and versatile coordination modes at rhodium.', Chemical communications., 52 (38). pp. 6443-6446.

Abstract

Four brand new hybrid ligands combining an N-heterocyclic carbene tethered with two isomeric nido-dicarbaundecaborane dianions, a neutral closo-dicarbadodecaborane or a closo-dicarbadodecaborane anion are described. Versatile coordination of the ligands to RhI is demonstrated, in which both NHC and carborane moieties covalently coordinate a metal centre.

Item Type:Article
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Status:Peer-reviewed
Publisher Web site:http://dx.doi.org/10.1039/C6CC01650B
Publisher statement:This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Date accepted:12 April 2016
Date deposited:29 April 2016
Date of first online publication:21 April 2016
Date first made open access:12 April 2017

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