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Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

Manson, Jamie L.; Schlueter, John A.; Garrett, Kerry E.; Goddard, Paul A.; Lancaster, Tom; Möller, Johannes S.; Blundell, Stephen J.; Steele, Andrew J.; Franke, Isabel; Pratt, Francis L.; Singleton, John; Bendix, Jesper; Lapidus, Saul H.; Uhlarz, Marc; Ayala-Valenzuela, Oscar; McDonald, Ross D.; Gurak, Mary; Baines, Christopher

Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system Thumbnail


Authors

Jamie L. Manson

John A. Schlueter

Kerry E. Garrett

Paul A. Goddard

Johannes S. Möller

Stephen J. Blundell

Andrew J. Steele

Isabel Franke

Francis L. Pratt

John Singleton

Jesper Bendix

Saul H. Lapidus

Marc Uhlarz

Oscar Ayala-Valenzuela

Ross D. McDonald

Mary Gurak

Christopher Baines



Abstract

The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n− octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.

Citation

Manson, J. L., Schlueter, J. A., Garrett, K. E., Goddard, P. A., Lancaster, T., Möller, J. S., …Baines, C. (2016). Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system. Chemical Communications, 52(85), 12653-12656. https://doi.org/10.1039/c6cc05873f

Journal Article Type Article
Acceptance Date Sep 27, 2016
Online Publication Date Sep 27, 2016
Publication Date Nov 4, 2016
Deposit Date Oct 18, 2016
Publicly Available Date Mar 28, 2024
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 52
Issue 85
Pages 12653-12656
DOI https://doi.org/10.1039/c6cc05873f

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