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Recyclable palladium catalyst cloths for carbon-carbon coupling reactions

Wilson, M.; Kore, R.; Fraser, R.C.; Beaumont, S.K.; Srivastava, R.; Badyal, J.P.S.

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Authors

M. Wilson

R. Kore

R.C. Fraser

R. Srivastava



Abstract

Low loading palladium catalyst cloths have been prepared by surface complexation of palladium(II) chloride with plasmachemical imidazole functionalised non-woven polypropylene cloth. For Sonogashira, Mizoroki-Heck, and Suzuki-Miyaura carbon-carbon coupling reactions in conjunction with environmentally friendly solvents, high product yields (54%, 82%, and 99% respectively) and selectivities (99%, 93%, and greater than 99% respectively) have been measured. These palladium catalyst cloths show low levels of metal leaching and can be recycled multiple times.

Citation

Wilson, M., Kore, R., Fraser, R., Beaumont, S., Srivastava, R., & Badyal, J. (2017). Recyclable palladium catalyst cloths for carbon-carbon coupling reactions. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 520, 788-795. https://doi.org/10.1016/j.colsurfa.2017.01.050

Journal Article Type Article
Acceptance Date Jan 18, 2017
Online Publication Date Jan 22, 2017
Publication Date May 5, 2017
Deposit Date Feb 28, 2017
Publicly Available Date Jan 22, 2018
Journal Colloids and Surfaces A: Physicochemical and Engineering Aspects
Print ISSN 0927-7757
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 520
Pages 788-795
DOI https://doi.org/10.1016/j.colsurfa.2017.01.050

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