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Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes.

Mason, Kevin and Harnden, Alice C. and Patrick, Connor W. and Poh, Adeline W. J. and Batsanov, Andrei S. and Suturina, Elizaveta A. and Vonci, Michele and McInnes, Eric J. L. and Chilton, Nicholas F. and Parker, David (2018) 'Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes.', Chemical communications., 54 (61). pp. 8486-8489.

Abstract

Crystallographic, emission and NMR studies of a series of C3-symmetric, nine-coordinate substituted pyridyl triazacyclononane Yb(III) and Eu(III) complexes reveal the impact of local solvation and ligand dipolar polarisability on ligand field strength, leading to dramatic variations in pseudocontact NMR shifts and emission spectral profiles, giving new guidance for responsive NMR and spectral probe design.

Item Type:Article
Full text:(AM) Accepted Manuscript
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Status:Peer-reviewed
Publisher Web site:https://doi.org/10.1039/C8CC04995E
Date accepted:10 July 2018
Date deposited:19 July 2018
Date of first online publication:10 July 2018
Date first made open access:10 July 2019

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