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Highly linearized twisted iridium(III) complexes.

Davidson, Ross and Hsu, Yu-Ting and Griffiths, Gareth C. and Li, Chenfei and Yufit, Dmitry and Pal, Robert and Beeby, Andrew (2018) 'Highly linearized twisted iridium(III) complexes.', Inorganic chemistry., 57 (22). pp. 14450-14462.

Abstract

Sonogashira coupling with alkyne iridium(phenylpyridine)2(acetylacetone) synthons is used to produce highly linearized twisted iridium(III) complexes with lengths of up to 5 nm. These complexes were mechanically aligned in a polymer matrix, showing an improved contrast ratio with increased length.

Item Type:Article
Full text:Publisher-imposed embargo until 01 November 2019.
(AM) Accepted Manuscript
First Live Deposit - 02 November 2018
File format - PDF
(1329Kb)
Full text:Publisher-imposed embargo until 01 November 2019.
(AM) Accepted Manuscript
First Live Deposit - 02 November 2018
File format - PDF (Supporting Information)
(5594Kb)
Status:Peer-reviewed
Publisher Web site:https://doi.org/10.1021/acs.inorgchem.8b02818
Publisher statement:This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.8b02818.
Record Created:02 Nov 2018 16:28
Last Modified:19 Nov 2018 10:01

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