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Highly Linearized Twisted Iridium(III) Complexes

Davidson, Ross; Hsu, Yu-Ting; Griffiths, Gareth C.; Li, Chenfei; Yufit, Dmitry; Pal, Robert; Beeby, Andrew

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Authors

Yu-Ting Hsu

Gareth C. Griffiths

Chenfei Li



Abstract

Sonogashira coupling with alkyne iridium(phenylpyridine)2(acetylacetone) synthons is used to produce highly linearized twisted iridium(III) complexes with lengths of up to 5 nm. These complexes were mechanically aligned in a polymer matrix, showing an improved contrast ratio with increased length.

Citation

Davidson, R., Hsu, Y., Griffiths, G. C., Li, C., Yufit, D., Pal, R., & Beeby, A. (2018). Highly Linearized Twisted Iridium(III) Complexes. Inorganic Chemistry, 57(22), 14450-14462. https://doi.org/10.1021/acs.inorgchem.8b02818

Journal Article Type Article
Acceptance Date Oct 25, 2018
Online Publication Date Nov 1, 2018
Publication Date Nov 19, 2018
Deposit Date Nov 2, 2018
Publicly Available Date Mar 29, 2024
Journal Inorganic Chemistry
Print ISSN 0020-1669
Electronic ISSN 1520-510X
Publisher American Chemical Society
Peer Reviewed Peer Reviewed
Volume 57
Issue 22
Pages 14450-14462
DOI https://doi.org/10.1021/acs.inorgchem.8b02818

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Copyright Statement
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.8b02818.


Accepted Journal Article (Supporting Information) (5.7 Mb)
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