Skip to main content

Research Repository

Advanced Search

The impact of replacement of nitrogen with phosphorus atom in the pyromellitic diimides on their photophysical and electrochemical properties

Pluczyk, Sandra; Higginbotham, Heather; Data, Przemyslaw; Takeda, Youhei; Minakata, Satoshi

The impact of replacement of nitrogen with phosphorus atom in the pyromellitic diimides on their photophysical and electrochemical properties Thumbnail


Authors

Sandra Pluczyk

Heather Higginbotham

Przemyslaw Data

Youhei Takeda

Satoshi Minakata



Abstract

Exploration of optoelectronic properties of novel phosphorus-embedded π-conjugated compounds would provide us with fundamental information about the design of hitherto unknown electroactive organic materials. Herein, detailed photophysical and electrochemical profiles of a series of benzene-cored diketophosphanyl compounds were investigated with steady- and time-resolved spectroscopic and spectroelectrochemical techniques. The comparative studies revealed the impact of phosphorus and nitrogen atoms on their triplet energies and on the behaviour of electrochemical processes to form radical species.

Citation

Pluczyk, S., Higginbotham, H., Data, P., Takeda, Y., & Minakata, S. (2019). The impact of replacement of nitrogen with phosphorus atom in the pyromellitic diimides on their photophysical and electrochemical properties. Electrochimica Acta, 295, 801-809. https://doi.org/10.1016/j.electacta.2018.10.156

Journal Article Type Article
Acceptance Date Oct 25, 2018
Online Publication Date Nov 5, 2018
Publication Date Feb 1, 2019
Deposit Date Nov 6, 2018
Publicly Available Date Nov 5, 2019
Journal Electrochimica Acta
Print ISSN 0013-4686
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 295
Pages 801-809
DOI https://doi.org/10.1016/j.electacta.2018.10.156

Files





You might also like



Downloadable Citations