Joshua S. Sapsford
Cp*Fe(Me2PCH2CH2PMe2)(CHO): Hydride shuttle reactivity of a thermally stable formyl complex
Sapsford, Joshua S.; Gates, Sarah J.; Doyle, Laurence R.; Taylor, Russell A.; Díez-González, Silvia; Ashley, Andrew E.
Authors
Sarah J. Gates
Laurence R. Doyle
Dr Russell Taylor russell.taylor@durham.ac.uk
Associate Professor
Silvia Díez-González
Andrew E. Ashley
Abstract
[Cp*Fe(Me2PCH2CH2PMe2)(CO)]+ [BArF24]− has been synthesised and characterised using single crystal X-ray diffraction, NMR and IR spectroscopies. Reduction of the CO ligand using Na[Et3BH] produces the corresponding neutral formyl complex Cp*Fe(Me2PCH2CH2PMe2)(CHO), that is very thermally stable, and which is attributed to the electron-releasing properties of the spectator ligands. This compound is a potent hydride donor which exists in equilibrium with [Et3BH]−, Et3B, and the structural isomer (η4-C5Me5H)Cp*Fe(Me2PCH2CH2PMe2)(CO), resulting from reversible hydride migration to the Cp* ligand.
Citation
Sapsford, J. S., Gates, S. J., Doyle, L. R., Taylor, R. A., Díez-González, S., & Ashley, A. E. (2019). Cp*Fe(Me2PCH2CH2PMe2)(CHO): Hydride shuttle reactivity of a thermally stable formyl complex. Inorganica Chimica Acta, 488, 201-207. https://doi.org/10.1016/j.ica.2019.01.022
Journal Article Type | Article |
---|---|
Acceptance Date | Jan 17, 2019 |
Online Publication Date | Jan 18, 2019 |
Publication Date | Mar 24, 2019 |
Deposit Date | Feb 12, 2019 |
Publicly Available Date | Jan 18, 2020 |
Journal | Inorganica Chimica Acta |
Print ISSN | 0020-1693 |
Publisher | Elsevier |
Peer Reviewed | Peer Reviewed |
Volume | 488 |
Pages | 201-207 |
DOI | https://doi.org/10.1016/j.ica.2019.01.022 |
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http://creativecommons.org/licenses/by-nc-nd/4.0/
Copyright Statement
© 2019 This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
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