An enantiopure cyclometallated iridium complex displaying long-lived phosphorescence both in solution and in the solid state

Crassous, Jeanne; Macé, Aurélie; Hellou, Nora; Hammoud, Joanna; Martin, Clothilde; Nasser, Ghassan; Gauthier, Etienne; Favereau, Ludovic; Roisnel, Thierry; Caytan, Elsa; Vanthuyne, Nicolas; Williams, Gareth; Berrée, Fabienne; Carboni, Bertrand

doi:10.1002/hlca.201900044

An enantiopure cyclometallated iridium complex displaying long-lived phosphorescence both in solution and in the solid state

Crassous, Jeanne; Macé, Aurélie; Hellou, Nora; Hammoud, Joanna; Martin, Clothilde; Nasser, Ghassan; Gauthier, Etienne; Favereau, Ludovic; Roisnel, Thierry; Caytan, Elsa; Vanthuyne, Nicolas; Williams, Gareth; Berrée, Fabienne; Carboni, Bertrand

Authors

Jeanne Crassous

Aurélie Macé

Nora Hellou

Joanna Hammoud

Clothilde Martin

Ghassan Nasser

Etienne Gauthier

Ludovic Favereau

Thierry Roisnel

Elsa Caytan

Nicolas Vanthuyne

Professor Gareth Williams j.a.g.williams@durham.ac.uk
Professor

Fabienne Berrée

Bertrand Carboni

Abstract

A new enantiopure cyclometallated iridium complex bearing a [4]helicenic :C^C– and two :N^C– dfppy (2‐(2,4‐difluorophenyl)‐pyridyl) ligands was prepared. This complex revealed a long‐lived phosphorescence both in solution and in the solid state. Its chiroptical properties, namely electronic circular dichroism and circularly polarized luminescence, were also examined. Comparison with former chiral complexes enabled assignment of the Delta‐Ir‐(‐) and Lambda‐Ir‐(+) absolute configurations.

Citation

Crassous, J., Macé, A., Hellou, N., Hammoud, J., Martin, C., Nasser, G., …Carboni, B. (2019). An enantiopure cyclometallated iridium complex displaying long-lived phosphorescence both in solution and in the solid state. Helvetica Chimica Acta, 102(4), https://doi.org/10.1002/hlca.201900044

Journal Article Type	Article
Acceptance Date	Feb 28, 2019
Online Publication Date	Mar 21, 2019
Publication Date	Apr 30, 2019
Deposit Date	Mar 1, 2019
Publicly Available Date	Feb 28, 2020
Journal	Helvetica Chimica Acta
Print ISSN	0018-019X
Electronic ISSN	1522-2675
Publisher	Wiley
Peer Reviewed	Peer Reviewed
Volume	102
Issue	4
DOI	https://doi.org/10.1002/hlca.201900044

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Copyright Statement
This is the accepted version of the following article: Crassous, Jeanne, Macé, Aurélie, Hellou, Nora, Hammoud, Joanna, Martin, Clothilde, Nasser, Ghassan, Gauthier, Etienne, Favereau, Ludovic, Roisnel, Thierry, Caytan, Elsa, Vanthuyne, Nicolas, Williams, Gareth, Berrée, Fabienne & Carboni, Bertrand (2019). An enantiopure cyclometallated iridium complex displaying long-lived phosphorescence both in solution and in the solid state. Helvetica Chimica Acta 102(4): e1900044 which has been published in final form at https://doi.org/10.1002/hlca.201900044. This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.