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Unravelling the complexities of pseudocontact shift analysis in lanthanide coordination complexes of differing symmetry.

Parker, David and Suturina, Elizaveta and Harnden, Alice and Batsanov, Andrei and Fox, Mark and Mason, Kevin and Vonci, Michele and McInnes, Eric and Chilton, Nicholas (2019) 'Unravelling the complexities of pseudocontact shift analysis in lanthanide coordination complexes of differing symmetry.', Angewandte Chemie., 131 (30). pp. 10936-10400.

Abstract

In two closely related series of eight‐coordinate lanthanide complexes, a switch in the sign of the dominant ligand field parameter and striking variations in the sign, amplitude and orientation of the main component of the magnetic susceptibility tensor as the Ln3+ ion is permuted conspire to mask modest changes in NMR paramagnetic shifts, but are evident in Yb EPR and Eu emission spectra.

Item Type:Article
Full text:(AM) Accepted Manuscript
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Status:Peer-reviewed
Publisher Web site:https://doi.org/10.1002/anie.201906031
Publisher statement:This is the accepted version of the following article: Parker, David, Suturina, Elizaveta, Harnden, Alice, Batsanov, Andrei, Fox, Mark, Mason, Kevin, Vonci, Michele, McInnes, Eric & Chilton, Nicholas (2019). Unravelling the Complexities of Pseudocontact Shift Analysis in Lanthanide Coordination Complexes of Differing Symmetry. Angewandte Chemie 131(30): 10396-10400., which has been published in final form at https://doi.org/10.1002/anie.201906031. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for self-archiving.
Date accepted:28 May 2019
Date deposited:30 May 2019
Date of first online publication:29 May 2019
Date first made open access:29 May 2020

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