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Variable temperature structural study of bismuth lead vanadate, BiPb₂VO₆

Evans, I.R.; Evans, J.S.O.; Howard, J.A.K.

Authors

J.A.K. Howard



Abstract

At room temperature, monoclinic BiPb2VO6 is a polar, noncentrosymmetric, second harmonic generation active material and its crystal structure is among the more complex to be solved ab initio from powder diffraction data. In its stability range, BiPb2VO6 also exists in a high symmetry, orthorhombic form. Both phases have been structurally characterized by a combination of X-ray and neutron diffraction data. Their mutual relationship, as well as that to the known compounds of the BiM(2)AO(6) (M = Mg, Ca, Mn, Cu, Zn, Pb and A = P, V, As) family, has been established.

Citation

Evans, I., Evans, J., & Howard, J. (2002). Variable temperature structural study of bismuth lead vanadate, BiPb₂VO₆. Journal of materials chemistry, 12(9), 2648-2652. https://doi.org/10.1039/b202648a

Journal Article Type Article
Publication Date 2002
Deposit Date Apr 5, 2007
Journal Journal of Materials Chemistry
Print ISSN 0959-9428
Electronic ISSN 1364-5501
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 12
Issue 9
Pages 2648-2652
DOI https://doi.org/10.1039/b202648a


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