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New group 15 compounds containing the 2,4,6-(CF3)(3)C6H2(fluoromes = Ar), 2,6-(CF3)(2)C6H3 (fluoroxyl = Ar ') or 2,4-(CF3)(2)C6H3 (Ar '') ligands

Batsanov, A.S.; Cornet, S.M.; Dillon, K.B.; Goeta, A.E.; Hazendonk, P.; Thompson, A.L.

Authors

A.S. Batsanov

S.M. Cornet

K.B. Dillon

A.E. Goeta

P. Hazendonk

A.L. Thompson



Abstract

Several new P or As compounds containing the 2,4,6-(CF3)(3)C6H2 (Ar), 2,6-(CF3)(2)C6H3 (Ar') and/or 2,4-(CF3)(2)C6H3 (Ar") ligands have been synthesised, and characterised by multinuclear NMR spectroscopy and (for all isolated compounds) elemental analysis. The crystal and molecular structures of ArPBr2 1, Ar2PCl 2, Ar-2"PCl3, Ar-2" PBr 4, Ar'Ar"AsCl 5, Ar'Ar"AsBr 6 and Ar'Ar"AsH 7 have been determined by single-crystal X-ray diffraction. A particularly interesting feature of these structures is close contacts between ortho-fluorines and the P or As atoms, as observed previously in Ar'Ar"PCl and Ar2AsCl.

Citation

Batsanov, A., Cornet, S., Dillon, K., Goeta, A., Hazendonk, P., & Thompson, A. (2002). New group 15 compounds containing the 2,4,6-(CF3)(3)C6H2(fluoromes = Ar), 2,6-(CF3)(2)C6H3 (fluoroxyl = Ar ') or 2,4-(CF3)(2)C6H3 (Ar '') ligands. Dalton Transactions, 24, 4622-4628. https://doi.org/10.1039/b207327g

Journal Article Type Article
Publication Date 2002-11
Deposit Date Apr 12, 2007
Journal Dalton Transactions
Print ISSN 1477-9226
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 24
Pages 4622-4628
DOI https://doi.org/10.1039/b207327g