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The identification of some novel four-membered ring cyclic triphosphenium ions in solution

Dillon, K.B.; Monks, P.K.; Olivey, R.J.; Karsch, H.H.

Authors

K.B. Dillon

P.K. Monks

R.J. Olivey

H.H. Karsch



Abstract

The first four-membered ring cyclic triphosphenium ions with carbon substituents (methyl or cyclohexyl) on the outer phosphorus atoms have been identified in solution by P-31 NMR spectroscopy. The cyclohexyl derivative in the presence of [SnCl6](2-) as counterion was stable enough for methylation by methyl triflate to be carried out.

Citation

Dillon, K., Monks, P., Olivey, R., & Karsch, H. (2004). The identification of some novel four-membered ring cyclic triphosphenium ions in solution. Heteroatom Chemistry, 15(6), 464-467. https://doi.org/10.1002/hc.20043

Journal Article Type Article
Publication Date 2004-09
Deposit Date Apr 20, 2007
Journal Heteroatom Chemistry
Print ISSN 1042-7163
Electronic ISSN 1098-1071
Publisher Hindawi
Peer Reviewed Peer Reviewed
Volume 15
Issue 6
Pages 464-467
DOI https://doi.org/10.1002/hc.20043

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