Dr Mark Fox m.a.fox@durham.ac.uk
Assistant Professor
Cage C---H...X interactions in solid-state structures of icosahedral carboranes
Fox, M.A.; Hughes, A.K.
Authors
A.K. Hughes
Abstract
This review probes C---HX interactions involving the acidic cage-carbon C---H bonds in ortho-, meta- and para-carboranes, closo-C2B10H12, and their derivatives, by examining the structurally characterised examples from the Cambridge Structural Database and other sources. Examples are examined of weak hydrogen bonds to X=O, N, S, F, Cl, Br, I, plus alkyne, cyclopentadienyl and arene-π systems. In addition there are examples of C---HH-X dihydrogen bonding. Cage C---HX interactions can be used to account for the observation of ordered structures in examples of carboranes where disorder of C and B cage atoms is possible.
Citation
Fox, M., & Hughes, A. (2004). Cage C---H...X interactions in solid-state structures of icosahedral carboranes. Coordination Chemistry Reviews, 248(5-6), 457-476. https://doi.org/10.1016/j.ccr.2003.10.002
| Journal Article Type | Article |
|---|---|
| Publication Date | 2004-03 |
| Deposit Date | Apr 25, 2007 |
| Journal | Coordination Chemistry Reviews |
| Print ISSN | 0010-8545 |
| Publisher | Elsevier |
| Peer Reviewed | Peer Reviewed |
| Volume | 248 |
| Issue | 5-6 |
| Pages | 457-476 |
| DOI | https://doi.org/10.1016/j.ccr.2003.10.002 |
| Keywords | Icosahedral carboranes, C---Hcdots, Three dots, CenteredX interactions, Crystal structures. |
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