Cookies

We use cookies to ensure that we give you the best experience on our website. By continuing to browse this repository, you give consent for essential cookies to be used. You can read more about our Privacy and Cookie Policy.


Durham Research Online
You are in:

Gas adsorption sites in a large-pore metal-organic framework.

Rowsell, J. L. C. and Spencer, E. C. and Eckert, J. and Howard, J. A. K. and Yaghi, O. M. (2005) 'Gas adsorption sites in a large-pore metal-organic framework.', Science., 309 (5739). pp. 1350-1354.

Abstract

The primary adsorption sites for Ar and N-2 within metal-organic framework-5, a cubic structure composed of Zn4O(CO2)(6) units and phenylene links defining large pores 12 and 15 angstroms in diameter, have been identified by single-crystal x-ray diffraction. Refinement of data collected between 293 and 30 kelvin revealed a total of eight symmetry-independent adsorption sites. Five of these are sites on the zinc oxide unit and the organic link; the remaining three sites form a second layer in the pores. The structural integrity and high symmetry of the framework are retained throughout, with-negligible changes resulting from gas adsorption.

Item Type:Article
Full text:Full text not available from this repository.
Publisher Web site:http://dx.doi.org/10.1126/science.1113247
Record Created:03 May 2007
Last Modified:08 Apr 2009 16:30

Social bookmarking: del.icio.usConnoteaBibSonomyCiteULikeFacebookTwitterExport: EndNote, Zotero | BibTex
Usage statisticsLook up in GoogleScholar | Find in a UK Library