Sellars, J. D. and Steel, P. G. and Turner, M. J. (2006) 'Hosomi-Sakurai reactions of silacyclic allyl silanes.', Chemical communications. (22). pp. 2385-2387.
Substituted silacyclohexenes, generated through silene–diene [4 + 2] cycloaddition reactions, undergo Lewis acid promoted Sakurai type reactions with acetals to afford, following oxidation of the resultant fluorosilane, 1,4-diols with four contiguous chiral centres.
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|Publisher Web site:||http://dx.doi.org/10.1039/b602642g|
|Record Created:||04 May 2007|
|Last Modified:||08 Apr 2009 16:30|
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