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Hosomi-Sakurai reactions of silacyclic allyl silanes.

Sellars, J. D. and Steel, P. G. and Turner, M. J. (2006) 'Hosomi-Sakurai reactions of silacyclic allyl silanes.', Chemical communications. (22). pp. 2385-2387.


Substituted silacyclohexenes, generated through silene–diene [4 + 2] cycloaddition reactions, undergo Lewis acid promoted Sakurai type reactions with acetals to afford, following oxidation of the resultant fluorosilane, 1,4-diols with four contiguous chiral centres.

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Record Created:04 May 2007
Last Modified:08 Apr 2009 16:30

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