Goeta, A. E. and Howard, J. A. K. and Hughes, A. K. and O'Hare, D. and Copley, R. C. B. (2007) 'Structural-magnetic correlations on the first dinuclear spin crossover d4 system.', Journal of materials chemistry., 17 (5). pp. 485-492.
The triple decker dinuclear Cr(II) salt [(5-C5Me5)Cr(µ2:5-P5)Cr(5-C5Me5)]+ (SbF6)– has been structurally characterised by multiple temperature X-ray diffraction experiments from 290 K to 12 K. This material shows changes in its structural features which correlate with its magnetic response, including a structural transition with a change of symmetry from the orthorhombic space group Fddd to the monoclinic I2/a at 160 K and an abrupt rearrangement of electron density at 23 K.
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|Publisher Web site:||http://dx.doi.org/10.1039/b612121g|
|Record Created:||10 May 2007|
|Last Modified:||08 Apr 2009 16:31|
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