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Structural-magnetic correlations on the first dinuclear spin crossover d⁴ system

Goeta, A.E.; Howard, J.A.K.; Hughes, A.K.; O'Hare, D.; Copley, R.C.B.

Authors

A.E. Goeta

J.A.K. Howard

A.K. Hughes

D. O'Hare

R.C.B. Copley



Abstract

The triple decker dinuclear Cr(II) salt [(5-C5Me5)Cr(µ2:5-P5)Cr(5-C5Me5)]+ (SbF6)– has been structurally characterised by multiple temperature X-ray diffraction experiments from 290 K to 12 K. This material shows changes in its structural features which correlate with its magnetic response, including a structural transition with a change of symmetry from the orthorhombic space group Fddd to the monoclinic I2/a at 160 K and an abrupt rearrangement of electron density at 23 K.

Citation

Goeta, A., Howard, J., Hughes, A., O'Hare, D., & Copley, R. (2007). Structural-magnetic correlations on the first dinuclear spin crossover d⁴ system. Journal of materials chemistry, 17(5), 485-492. https://doi.org/10.1039/b612121g

Journal Article Type Article
Publication Date Nov 1, 2007
Deposit Date May 10, 2007
Journal Journal of Materials Chemistry
Print ISSN 0959-9428
Electronic ISSN 1364-5501
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 17
Issue 5
Pages 485-492
DOI https://doi.org/10.1039/b612121g

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