Cookies

We use cookies to ensure that we give you the best experience on our website. You can change your cookie settings at any time. Otherwise, we'll assume you're OK to continue.


Durham Research Online
You are in:

Stereochemistry of the reaction of Si-phenyl silenes with butadienes : elaboration of the silacycloadducts to provide a novel route to substituted lactones.

Sanganee, M. J. and Steel, P. G. and Whelligan, D. K. (2004) 'Stereochemistry of the reaction of Si-phenyl silenes with butadienes : elaboration of the silacycloadducts to provide a novel route to substituted lactones.', Organic & biomolecular chemistry., 2 (16). pp. 2393-2402.

Abstract

Silenes generated through a silyl-modified Peterson olefination procedure can be trapped with a range of alkyl butadienes via a [4+2] cycloaddition pathway to afford silacycles accompanied by variable amounts of competing ene, [2+2] and silene dimer by-products. The silacycles are formed with good chemo- and stereo-selectivity and provide access to diols and lactones via a phenyl-triggered Fleming-Tamao oxidation.

Item Type:Article
Full text:Full text not available from this repository.
Publisher Web site:http://dx.doi.org/ 10.1039/B404175E
Record Created:10 May 2007
Last Modified:08 Apr 2009 16:31

Social bookmarking: del.icio.usConnoteaBibSonomyCiteULikeFacebookTwitterExport: EndNote, Zotero | BibTex
Usage statisticsLook up in GoogleScholar | Find in a UK Library