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Polyhalogenated heterocyclic compounds : macrocycles from perfluoro-4-isopropylpyridine.

Chambers, R. D. and Hoskin, P. R. and Kenwright, A. R. and Khalil, A. and Richmond, P. and Sandford, G. and Yufit, D. S. and Howard, J. A. K. (2003) 'Polyhalogenated heterocyclic compounds : macrocycles from perfluoro-4-isopropylpyridine.', Organic & biomolecular chemistry., 1 (12). pp. 2137-2147.


Perfluoro-4-isopropylpyridine was used as a building block for the two-step synthesis of a variety of macrocyclic systems bearing pyridine sub-units which were characterised by X-ray crystallography. Electrospray mass spectrometry revealed that complexation of either cations and, unusually, anions is possible depending on the structure of the macrocycle.

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Record Created:09 Jan 2009
Last Modified:08 Apr 2009 16:31

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