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Carborane radical anions : spectroscopic and electronic properties of a carborane radical anion with a 2n + 3 skeletal electron count.

Fox, M. A. and Nervi, C. and Crivello, A.. and Low, P. J. (2007) 'Carborane radical anions : spectroscopic and electronic properties of a carborane radical anion with a 2n + 3 skeletal electron count.', Chemical communications., 23 . pp. 2372-2374.

Abstract

One-electron reduction of the well-known carborane 1,2-Ph2-1,2-C2B10H10 (1) gives rise to a stable carborane radical anion ([1]–) with a true 2n + 3 cluster electron count; the geometry of ([1]–) features an elongated CC cage distance but no significant -bonding interactions between the cage and the phenyl substituents.

Item Type:Article
Full text:PDF - Accepted Version (365Kb)
Status:Peer-reviewed
Publisher Web site:http://dx.doi.org/10.1039/b700110j
Record Created:21 Sep 2007
Last Modified:31 Jul 2014 15:52

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