Nahler, N. H. and Vieuxmaire, O. P. J. and Jones, J. R. and Ashfold, M. N. R. and Eppink, A. T. J. B. and Coriou, A. M. and Parker, D. H. (2004) 'High-resolution ion-imaging studies of the photodissociation of the BrCl+ Cation.', Journal of physical chemistry A., 108 (39). pp. 8077-8083.
The photofragmentation of state-selected BrCl+ cations has been investigated by velocity-map ion-imaging methods. Detailed analyses of the 79Br+ fragment velocities lead to the most precise values yet reported for (i) the spin-orbit coupling constant for the X2 state, A = -2070 ± 4 cm-1; (ii) the bond dissociation energies of both states of 79Br35Cl+, 25019 ± 4 cm-1 (X23/2) and 22949 ± 2 cm-1 (X21/2); and (iii) the adiabatic ionization thresholds for forming 79Br35Cl+ parent ions in their X23/2 and X21/2 states, 88292 ± 6 and 90362 ± 4 cm-1, respectively.
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|Publisher Web site:||http://dx.doi.org/10.1021/jp049238q|
|Record Created:||18 Jan 2008|
|Last Modified:||08 Apr 2009 16:37|
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