Hughes, N. J. and Pullin, R. D. C. and Sanganee, M. J. and Sellars, J. D. and Steel, P. G. and Turner, M. J. (2007) 'Hosomi-Sakurai reactions of silacyclohexenes.', Organic & biomolecular chemistry., 5 (17). pp. 2841-2848.
Abstract
Silacyclic allyl silanes, derived from silene–diene Diels–Alder reactions, combine with acetals in the presence of Lewis acids to afford, following oxidation of the intermediate fluorosilane, either butane-1,4-diols or tetrahydronaphthalenes containing four contiguous chiral centres with moderate to good diastereoselectivity.
| Item Type: | Article |
|---|---|
| Full text: | Full text not available from this repository. |
| Publisher Web site: | http://dx.doi.org/10.1039/b709318g |
| Record Created: | 18 Jan 2008 |
| Last Modified: | 22 Oct 2010 16:56 |
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