Hosomi-Sakurai Reactions of Silacyclohexenes

Hughes, N.J.; Pullin, R.D.C.; Sanganee, M.J.; Sellars, J.D.; Steel, P.G.; Turner, M.J.

doi:10.1039/b709318g

Hosomi-Sakurai Reactions of Silacyclohexenes

Hughes, N.J.; Pullin, R.D.C.; Sanganee, M.J.; Sellars, J.D.; Steel, P.G.; Turner, M.J.

Authors

N.J. Hughes

R.D.C. Pullin

M.J. Sanganee

J.D. Sellars

Professor Patrick Steel p.g.steel@durham.ac.uk
Professor

M.J. Turner

Abstract

Silacyclic allyl silanes, derived from silene–diene Diels–Alder reactions, combine with acetals in the presence of Lewis acids to afford, following oxidation of the intermediate fluorosilane, either butane-1,4-diols or tetrahydronaphthalenes containing four contiguous chiral centres with moderate to good diastereoselectivity.

Citation

Hughes, N., Pullin, R., Sanganee, M., Sellars, J., Steel, P., & Turner, M. (2007). Hosomi-Sakurai Reactions of Silacyclohexenes. Organic and Biomolecular Chemistry, 5(17), 2841-2848. https://doi.org/10.1039/b709318g

Journal Article Type	Article
Publication Date	Jul 1, 2007
Deposit Date	Jan 18, 2008
Journal	Organic and Biomolecular Chemistry
Print ISSN	1477-0520
Electronic ISSN	1477-0539
Publisher	Royal Society of Chemistry
Peer Reviewed	Peer Reviewed
Volume	5
Issue	17
Pages	2841-2848
DOI	https://doi.org/10.1039/b709318g