CE Willans
Deboronation and Deprotonation of ortho-Carborane with N-Heterocyclic Carbenes
Willans, CE; Kilner, CA; Fox, MA
Abstract
It is a matter of size: N-Heterocyclic carbenes can remove a proton from ortho-carborane to form a two-cage anion or attack the electropositive boron of ortho-carborane to yield a stable 1:2 carborane–carbene adduct. Which end product is formed depends on the steric bulk of the alkyl groups attached to the nitrogen atoms of the carbene.
Citation
Willans, C., Kilner, C., & Fox, M. (2010). Deboronation and Deprotonation of ortho-Carborane with N-Heterocyclic Carbenes. Chemistry - A European Journal, 16(35), 10644-10648. https://doi.org/10.1002/chem.201001730
| Journal Article Type | Article |
|---|---|
| Publication Date | Sep 17, 2010 |
| Deposit Date | Dec 14, 2011 |
| Journal | Chemistry - A European Journal |
| Print ISSN | 0947-6539 |
| Electronic ISSN | 1521-3765 |
| Publisher | Wiley |
| Peer Reviewed | Peer Reviewed |
| Volume | 16 |
| Issue | 35 |
| Pages | 10644-10648 |
| DOI | https://doi.org/10.1002/chem.201001730 |
| Keywords | Cage compounds, Carboranes, Cluster compounds, N-heterocyclic carbenes. |
You might also like
Vapor Sorption and Halogen-Bond-Induced Solid-Form Rearrangement of a Porous Pharmaceutical
(2023)
Journal Article
Tuning Emission Lifetimes of Ir(C^N)2(acac) Complexes with Oligo(phenyleneethynylene) Groups
(2023)
Journal Article
Downloadable Citations
About Durham Research Online (DRO)
Administrator e-mail: dro.admin@durham.ac.uk
This application uses the following open-source libraries:
SheetJS Community Edition
Apache License Version 2.0 (http://www.apache.org/licenses/)
PDF.js
Apache License Version 2.0 (http://www.apache.org/licenses/)
Font Awesome
SIL OFL 1.1 (http://scripts.sil.org/OFL)
MIT License (http://opensource.org/licenses/mit-license.html)
CC BY 3.0 ( http://creativecommons.org/licenses/by/3.0/)
Powered by Worktribe © 2024
Advanced Search