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Simple model for the deformation-induced relaxation of glassy polymers.

Fielding, S.M. and Larson, R.G. and Cates, M.E. (2012) 'Simple model for the deformation-induced relaxation of glassy polymers.', Physical review letters., 108 (4). 048301.

Abstract

Glassy polymers show “strain hardening”: at constant extensional load, their flow first accelerates, then arrests. Recent experiments have found this to be accompanied by a striking and unexplained dip in the segmental relaxation time. Here we explain such behavior by combining a minimal model of flow-induced liquefaction of a glass with a description of the stress carried by strained polymers, creating a nonfactorable interplay between aging and strain-induced rejuvenation. Under constant load, liquefaction of segmental motion permits strong flow that creates polymer-borne stress. This slows the deformation enough for the segmental modes to revitrify, causing strain hardening.

Item Type:Article
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Status:Peer-reviewed
Publisher Web site:http://dx.doi.org/10.1103/PhysRevLett.108.048301
Publisher statement:© 2012 American Physical Society
Date accepted:No date available
Date deposited:28 November 2012
Date of first online publication:January 2012
Date first made open access:No date available

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