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Reactions of ultracold alkali-metal dimers.

Zuchowski, Piotr S. and Hutson, Jeremy M. (2010) 'Reactions of ultracold alkali-metal dimers.', Physical review A., 81 (6). 060703.

Abstract

We investigate the energetics of reactions involving pairs of alkali-metal dimers. Atom exchange reactions to form homonuclear dimers are energetically allowed for some but not all of the heteronuclear dimers. We carry out high-level electronic structure calculations on the potential energy surfaces of all the heteronuclear alkali-metal trimers and show that trimer formation reactions are always energetically forbidden for low-lying singlet states of the dimers. The results have important implications for the stability of quantum gases of alkali-metal dimers.

Item Type:Article
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Status:Peer-reviewed
Publisher Web site:http://dx.doi.org/10.1103/PhysRevA.81.060703
Publisher statement:© 2010 The American Physical Society
Date accepted:No date available
Date deposited:27 June 2013
Date of first online publication:2010
Date first made open access:No date available

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