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Supramolecular gel phase crystallization : orthogonal self-assembly under non-equilibrium conditions.

Kumar, D. K. and Steed, J. W. (2014) 'Supramolecular gel phase crystallization : orthogonal self-assembly under non-equilibrium conditions.', Chemical society reviews., 44 . pp. 2080-2088.


This tutorial review charts the history of gel phase crystallization from its origins in Liesegang ring formation to current research in the generation of new pharmaceutical solid forms in low molecular weight organogels. The growth of molecular crystals under a supersaturation gradient within the same space and timescale as the formation of a gel phase material is placed into context as an example of orthogonal self-assembly. Such multi-component, weakly coupled orthogonal self-assembly processes occurring far from equilibrium represent a powerful conceptual paradigm for generating fascinating emergent behaviour in chemical systems.

Item Type:Article
Full text:(AM) Accepted Manuscript
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Date accepted:No date available
Date deposited:10 January 2014
Date of first online publication:August 2014
Date first made open access:No date available

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