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Supramolecular assembly in a Janus-type urea system.

Lloyd, Gareth O. and Steed, Jonathan W. (2014) 'Supramolecular assembly in a Janus-type urea system.', Chemical communications., 50 (12). pp. 1426-1428.

Abstract

A pyrazolyl urea ligand adopts two possible conformations with the urea NH groups directed either outward or inward. Metal coordination enforces the outward conformation resulting in either anion complexation or self-association and hence extended supramolecular assemblies including a hexameric barrel that persists in solution.

Item Type:Article
Full text:(AM) Accepted Manuscript
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Status:Peer-reviewed
Publisher Web site:http://dx.doi.org/10.1039/c3cc48603f
Date accepted:No date available
Date deposited:06 February 2014
Date of first online publication:February 2014
Date first made open access:No date available

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