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Pd-catalysed sp2-sp cross-coupling reactions involving aromatic C-F bond activation in highly fluorinated nitrobenzene systems.

Cargill, M.R. and Sandford, G. and Kilickiran, P. and Nelles, G. (2013) 'Pd-catalysed sp2-sp cross-coupling reactions involving aromatic C-F bond activation in highly fluorinated nitrobenzene systems.', Tetrahedron., 69 (2). pp. 512-516.

Abstract

Direct and regioselective alkynylation of highly fluorinated nitrobenzene derivatives by palladium-catalyzed Sonogashira type processes is described, representing the first examples of metal-catalyzed sp2–sp cross-coupling reactions involving C–F bond activation.

Item Type:Article
Full text:(AM) Accepted Manuscript
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Status:Peer-reviewed
Publisher Web site:http://dx.doi.org/10.1016/j.tet.2012.11.031
Publisher statement:NOTICE: this is the author’s version of a work that was accepted for publication in Tetrahedron. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Tetrahedron, 69, 2, 2013, 10.1016/j.tet.2012.11.031.
Date accepted:No date available
Date deposited:29 May 2014
Date of first online publication:January 2013
Date first made open access:No date available

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