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An unprecedented cyclometallated platinum(II)complex incorporating a phosphinine co-ligand : synthesis and photoluminescence behaviour.

Moussa, J. and Cheminel, T. and Freeman, G. R. and Chamoreau, L. M. and Williams, J. A. G. and Amouri, H. (2014) 'An unprecedented cyclometallated platinum(II)complex incorporating a phosphinine co-ligand : synthesis and photoluminescence behaviour.', Dalton transactions., 43 (22). pp. 8162-8165.

Abstract

The first luminescent cyclometallated platinum(II) complex bearing phosphinine co-ligands is reported. The long-lived luminescence, which it displays at 77 K, is assigned to a phosphinine-localised triplet excited state on the basis of electrochemical data and TD-DFT calculations.

Item Type:Article
Full text:(AM) Accepted Manuscript
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Status:Peer-reviewed
Publisher Web site:http://dx.doi.org/10.1039/c4dt00589a
Date accepted:14 March 2014
Date deposited:08 July 2014
Date of first online publication:14 March 2014
Date first made open access:No date available

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