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Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II).

Tuxworth, Luke and Baiget, Lise and Phanopoulos, Andreas and Metters, Owen J. and Batsanov, Andrei S. and Fox, Mark A. and Howard, Judith A. K. and Dyer, Philip W. (2012) 'Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II).', Chemical communications., 48 (84). pp. 10413-10415.


N-Diphenylphosphino-7-aza-benzobicyclo[2.2.1]hept-2-ene (2) behaves as a chelating phosphine–alkene ligand for Pd0 and PdII, promoting direct alkyl–alkyl and indirect alkyl–halide reductive elimination reactions due to the stabilisation of the resulting bis(phosphine–alkene)Pd0 complex.

Item Type:Article
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Date accepted:No date available
Date deposited:18 July 2014
Date of first online publication:September 2012
Date first made open access:No date available

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