Tuxworth, Luke and Baiget, Lise and Phanopoulos, Andreas and Metters, Owen J. and Batsanov, Andrei S. and Fox, Mark A. and Howard, Judith A. K. and Dyer, Philip W. (2012) 'Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II).', Chemical communications., 48 (84). pp. 10413-10415.
Abstract
N-Diphenylphosphino-7-aza-benzobicyclo[2.2.1]hept-2-ene (2) behaves as a chelating phosphine–alkene ligand for Pd0 and PdII, promoting direct alkyl–alkyl and indirect alkyl–halide reductive elimination reactions due to the stabilisation of the resulting bis(phosphine–alkene)Pd0 complex.
| Item Type: | Article |
|---|---|
| Full text: | (AM) Accepted Manuscript Download PDF (633Kb) |
| Status: | Peer-reviewed |
| Publisher Web site: | http://dx.doi.org/10.1039/c2cc35623f |
| Date accepted: | No date available |
| Date deposited: | 18 July 2014 |
| Date of first online publication: | September 2012 |
| Date first made open access: | No date available |
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