Tuxworth, Luke and Baiget, Lise and Phanopoulos, Andreas and Metters, Owen J. and Batsanov, Andrei S. and Fox, Mark A. and Howard, Judith A. K. and Dyer, Philip W. (2012) 'Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II).', Chemical communications., 48 (84). pp. 10413-10415.
N-Diphenylphosphino-7-aza-benzobicyclo[2.2.1]hept-2-ene (2) behaves as a chelating phosphine–alkene ligand for Pd0 and PdII, promoting direct alkyl–alkyl and indirect alkyl–halide reductive elimination reactions due to the stabilisation of the resulting bis(phosphine–alkene)Pd0 complex.
|Full text:||(AM) Accepted Manuscript|
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|Publisher Web site:||http://dx.doi.org/10.1039/c2cc35623f|
|Date accepted:||No date available|
|Date deposited:||18 July 2014|
|Date of first online publication:||September 2012|
|Date first made open access:||No date available|
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