M Trmčić
Synthesis of thiophosphoramidates in water: Click chemistry for phosphates
Trmčić, M; Hodgson, DRW
Abstract
An aqueous method for the preparation of N,S-dialkyl thiophosphoramidates is reported. Thiophosphorylation of alkylamines was performed using SPCl3 in aqueous reaction media, and the resulting thiophosphoramidate-S-anions were S-alkylated with soft electrophiles. Ranges of amines and electrophiles were explored.
Citation
Trmčić, M., & Hodgson, D. (2011). Synthesis of thiophosphoramidates in water: Click chemistry for phosphates. Chemical Communications, 47(21), 6156-6158. https://doi.org/10.1039/c1cc11586c
| Journal Article Type | Article |
|---|---|
| Publication Date | Jun 7, 2011 |
| Deposit Date | Feb 6, 2012 |
| Publicly Available Date | Nov 6, 2014 |
| Journal | Chemical Communications |
| Print ISSN | 1359-7345 |
| Electronic ISSN | 1364-548X |
| Publisher | Royal Society of Chemistry |
| Peer Reviewed | Peer Reviewed |
| Volume | 47 |
| Issue | 21 |
| Pages | 6156-6158 |
| DOI | https://doi.org/10.1039/c1cc11586c |
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