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Conserved hydrogen bonding in tetrahydrocarbazolone derivatives: influence of solution-state assembly on crystal form nucleation

Edkins, Robert M.; Hayden, Elliott; Steed, Jonathan W.; Fucke, Katharina

Conserved hydrogen bonding in tetrahydrocarbazolone derivatives: influence of solution-state assembly on crystal form nucleation Thumbnail


Authors

Robert M. Edkins

Elliott Hayden

Katharina Fucke



Abstract

Two tetrahydocarbazolone derivatives were found to show multiple unsolvated crystal forms. A persistent dimer motif was detected in solution by FTIR spectroscopy that is maintained in the kinetic crystal forms. Rationally introduced steric bulk induces the formation of a more stable catemeric form.

Citation

Edkins, R. M., Hayden, E., Steed, J. W., & Fucke, K. (2015). Conserved hydrogen bonding in tetrahydrocarbazolone derivatives: influence of solution-state assembly on crystal form nucleation. Chemical Communications, 51(25), 5314-5317. https://doi.org/10.1039/c4cc10453f

Journal Article Type Article
Acceptance Date Feb 10, 2015
Publication Date Mar 28, 2015
Deposit Date Mar 2, 2015
Publicly Available Date Mar 29, 2024
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 51
Issue 25
Pages 5314-5317
DOI https://doi.org/10.1039/c4cc10453f

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Copyright Statement
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.






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