E. La Cascia
Asymmetric metal free β-boration of α,β-unsaturated imines assisted by (S)-MeBoPhoz
La Cascia, E.; Sanz, X.; Bo, C.; Whiting, A.; Fernandez, E.
Authors
Abstract
The adduct [MeO → Bpin–Bpin]− efficiently mediates the β-boration of α,β-unsaturated imines formed in situ. The use of chiral phosphines as additives, and in particular the chiral phosphine (S)-MeBoPhoz, enables the catalytic asymmetric reaction to proceed with higher enantioselectivity than the analogue copper(I) mediated reaction.
Citation
La Cascia, E., Sanz, X., Bo, C., Whiting, A., & Fernandez, E. (2014). Asymmetric metal free β-boration of α,β-unsaturated imines assisted by (S)-MeBoPhoz. Organic and Biomolecular Chemistry, 13(5), 1328-1332. https://doi.org/10.1039/c4ob02478h
| Journal Article Type | Article |
|---|---|
| Acceptance Date | Dec 10, 2014 |
| Publication Date | Feb 7, 2014 |
| Deposit Date | Dec 15, 2014 |
| Publicly Available Date | Mar 26, 2015 |
| Journal | Organic and Biomolecular Chemistry |
| Print ISSN | 1477-0520 |
| Electronic ISSN | 1477-0539 |
| Publisher | Royal Society of Chemistry |
| Peer Reviewed | Peer Reviewed |
| Volume | 13 |
| Issue | 5 |
| Pages | 1328-1332 |
| DOI | https://doi.org/10.1039/c4ob02478h |
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