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Infinitely adaptive transition-metal ordering in Ln2O2MSe2-type oxychalcogenides.

Ainsworth, Chris M. and Wang, Chun-Hai and Johnston, Hannah E. and McCabe, Emma E. and Tucker, Matthew G. and Brand, Helen E. A. and Evans, John S. O. (2015) 'Infinitely adaptive transition-metal ordering in Ln2O2MSe2-type oxychalcogenides.', Inorganic chemistry., 54 (15). pp. 7230-7238.

Abstract

The origin of transition-metal ordering in Ln2O2MSe2 oxychalcogenides has been revealed by investigating a range of solid solutions. Transition-metal ordering is determined by the relative sizes of [Ln2O2]2+ and [MSe2]2− layers and can be exquisitely tuned by substitution in either layer, leading to an “infinitely adaptive” structural family. The proportion of the inherently smaller corner-shared motif increases as the transition-metal size increases relative to the lanthanide oxide layers.

Item Type:Article
Full text:(AM) Accepted Manuscript
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Status:Peer-reviewed
Publisher Web site:http://dx.doi.org/10.1021/acs.inorgchem.5b00599
Publisher statement:This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © 2015 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/acs.inorgchem.5b00599.
Date accepted:16 March 2015
Date deposited:06 May 2015
Date of first online publication:30 April 2015
Date first made open access:30 April 2016

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