J.J. Shephard
Polar stacking of molecules in liquid chloroform
Shephard, J.J.; Soper, A.K.; Callear, S.K.; Imberti, S.; Evans, J.S.O.; Salzmann, C.G.
Authors
A.K. Soper
S.K. Callear
S. Imberti
Professor John Evans john.evans@durham.ac.uk
Professor
C.G. Salzmann
Abstract
Using neutron diffraction and the isotopic substitution technique we have investigated the local structure of liquid chloroform. A strong tendency for polar stacking of molecules with collinear alignment of dipole moments is found. We speculate that these polar stacks contribute to the performance of chloroform as a solvent.
Citation
Shephard, J., Soper, A., Callear, S., Imberti, S., Evans, J., & Salzmann, C. (2015). Polar stacking of molecules in liquid chloroform. Chemical Communications, 51(23), 4770-4773. https://doi.org/10.1039/c4cc09235j
Journal Article Type | Article |
---|---|
Publication Date | Mar 21, 2015 |
Deposit Date | May 4, 2015 |
Publicly Available Date | Mar 28, 2024 |
Journal | Chemical Communications |
Print ISSN | 1359-7345 |
Electronic ISSN | 1364-548X |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 51 |
Issue | 23 |
Pages | 4770-4773 |
DOI | https://doi.org/10.1039/c4cc09235j |
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