Roberts, G. M. and Lecointre, J. and Horke, D. A. and Verlet, J. R .R. (2010) 'Spectroscopy and dynamics of the 7,7,8,8-tetracyanoquinodimethane radical anion.', Physical chemistry chemical physics., 12 (23). pp. 6226-6232.
The photoelectron spectrum of the 7,7,8,8-tetracyanoquinodimethane (TCNQ) radical anion has been measured at 3.1 eV. Additionally, the ultrafast relaxation dynamics of the first excited state (12B3u) of TCNQ− have been studied using time-resolved photoelectron spectroscopy, which reveals that it undergoes internal conversion back to the ground state (2B2g) with an associated lifetime of 650 fs and shows evidence of coherent nuclear motion.
|Full text:||(AM) Accepted Manuscript|
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|Publisher Web site:||http://dx.doi.org/10.1039/c001438a|
|Date accepted:||26 March 2010|
|Date deposited:||05 February 2016|
|Date of first online publication:||June 2010|
|Date first made open access:||No date available|
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