Roberts, G. M. and Lecointre, J. and Horke, D. A. and Verlet, J. R .R. (2010) 'Spectroscopy and dynamics of the 7,7,8,8-tetracyanoquinodimethane radical anion.', Physical chemistry chemical physics., 12 (23). pp. 6226-6232.
Abstract
The photoelectron spectrum of the 7,7,8,8-tetracyanoquinodimethane (TCNQ) radical anion has been measured at 3.1 eV. Additionally, the ultrafast relaxation dynamics of the first excited state (12B3u) of TCNQ− have been studied using time-resolved photoelectron spectroscopy, which reveals that it undergoes internal conversion back to the ground state (2B2g) with an associated lifetime of 650 fs and shows evidence of coherent nuclear motion.
| Item Type: | Article |
|---|---|
| Full text: | (AM) Accepted Manuscript Download PDF (353Kb) |
| Status: | Peer-reviewed |
| Publisher Web site: | http://dx.doi.org/10.1039/c001438a |
| Date accepted: | 26 March 2010 |
| Date deposited: | 05 February 2016 |
| Date of first online publication: | June 2010 |
| Date first made open access: | No date available |
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