Cookies

We use cookies to ensure that we give you the best experience on our website. By continuing to browse this repository, you give consent for essential cookies to be used. You can read more about our Privacy and Cookie Policy.


Durham Research Online
You are in:

Antiferromagnetism in a Family of S = 1 Square Lattice Coordination Polymers NiX2(pyz)2 (X = Cl, Br, I, NCS; pyz = Pyrazine).

Liu, J. and Goddard, P.A. and Singleton, J. and Brambleby, J. and Foronda, F. and Moeller, J.S. and Kohama, Y. and Ghannadzadeh, S. and Ardavan, A. and Blundell, S.J. and Lancaster, T. and Xiao, F. and Williams, R.C. and Pratt, F.L. and Baker, P.J. and Wierschem, K. and Lapidus, S.H. and Stone, K.H. and Stephens, P.W. and Bendix, J and Woods, T.J. and Carreiro, K.E. and Tran, H.E. and Villa, C.J. and Manson, J.L. (2016) 'Antiferromagnetism in a Family of S = 1 Square Lattice Coordination Polymers NiX2(pyz)2 (X = Cl, Br, I, NCS; pyz = Pyrazine).', Inorganic chemistry., 55 (7). pp. 3515-3529.

Abstract

NiX2(pyz)2 have been synthesized and characterized using several magnetic probes. Except for X = Cl, long-range AFM order was found below TN = 1.9 (X = Br and NCS) and 2.5 K (X = I). In addition, Jpyz ∼ 1 K regardless of X, and D = 8 K for NiCl2(pyz)2, whereas D ∼ 0 for X = Br, I, and NCS based on ESR and heat capacity.

Item Type:Article
Full text:(NA) Not Applicable
Download PDF (arXiv version)
(1408Kb)
Status:Peer-reviewed
Publisher Web site:http://dx.doi.org/10.1021/acs.inorgchem.5b02991
Publisher statement:This document appeared in final form in Inorganic chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/acs.inorgchem.5b02991
Date accepted:30 December 2015
Date deposited:No date available
Date of first online publication:02 March 2016
Date first made open access:No date available

Save or Share this output

Export:
Export
Look up in GoogleScholar