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Modulating the hydration behaviour of calcium chloride by lactam complexation.

Perrin, Andrea and Musa, Osama M. and Steed, Jonathan W. (2016) 'Modulating the hydration behaviour of calcium chloride by lactam complexation.', Dalton transactions., 45 (30). pp. 12181-12187.

Abstract

Complexation of calcium chloride with bis(lactam) ligand L1 allows the formation of both an unstable anhydrous complex, an aqua complex {[Ca2(μ-L1)2(H2O)9]Cl4]}n (1) and a related hydrate incorporating additional lattice water of crystallization {[Ca(μ-L1)(H2O)5]Cl2·H2O}n (2). Related mono(lactam) L2 does not form aqua complexes but the anhydrous complex {[CaCl2(μ-L2)2]}n (3), is highly deliquescent. An unusual ethanol solvate is also reported {[CaCl2(L2)(EtOH)]}n (4).

Item Type:Article
Full text:(AM) Accepted Manuscript
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Status:Peer-reviewed
Publisher Web site:http://dx.doi.org/10.1039/C6DT02296K
Date accepted:06 July 2016
Date deposited:01 August 2016
Date of first online publication:07 July 2016
Date first made open access:06 July 2017

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