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Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1) : co-existence of ordered and disordered quantum spins in the V4+ system.

Manson, Jamie L. and Schlueter, John A. and Garrett, Kerry E. and Goddard, Paul A. and Lancaster, Tom and Möller, Johannes S. and Blundell, Stephen J. and Steele, Andrew J. and Franke, Isabel and Pratt, Francis L. and Singleton, John and Bendix, Jesper and Lapidus, Saul H. and Uhlarz, Marc and Ayala-Valenzuela, Oscar and McDonald, Ross D. and Gurak, Mary and Baines, Christopher (2016) 'Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1) : co-existence of ordered and disordered quantum spins in the V4+ system.', Chemical communications., 52 (85). pp. 12653-12656.

Abstract

The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n− octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.

Item Type:Article
Full text:(AM) Accepted Manuscript
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Status:Peer-reviewed
Publisher Web site:https://doi.org/10.1039/C6CC05873F
Date accepted:27 September 2016
Date deposited:28 October 2016
Date of first online publication:27 September 2016
Date first made open access:27 September 2017

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