Cookies

We use cookies to ensure that we give you the best experience on our website. By continuing to browse this repository, you give consent for essential cookies to be used. You can read more about our Privacy and Cookie Policy.


Durham Research Online
You are in:

PARASHIFT probes : solution NMR and X-ray structural studies of macrocyclic ytterbium and yttrium complexes.

Mason, K. and Rogers, N.J. and Suturina, E.A. and Kuprov, I. and Aguilar, J.A. and Batsanov, A.S. and Yufit, D.S. and Parker, D. (2017) 'PARASHIFT probes : solution NMR and X-ray structural studies of macrocyclic ytterbium and yttrium complexes.', Inorganic chemistry., 56 (7). pp. 4028-4038.

Abstract

Ytterbium and yttrium complexes of octadentate ligands based on 1,4,7,10-tetraazacyclododecane with a coordinated pyridyl group and either tricarboxylate (L1) or triphosphinate (L2) donors form twisted-square-antiprismatic structures. The former crystallizes in the centrosymmetric group P21/c, with the two molecules related by an inversion center, whereas the latter was found as an unusual kryptoracemate in the chiral space group P21. Pure shift NMR and EXSY spectroscopy allowed the dynamic exchange between the (RRR)-Δ-(δδδδ) and (RRR)-Λ-(λλλλ) TSAP diastereomers of the [Y.L2] complex to be detected. The rate-limiting step in the exchange between Δ and Λ isomers involves cooperative ligand arm rotation, which is much faster for [Ln.L1] than for [Ln.L2]. Detailed analysis of NOESY, COSY, HSQC, and HMBC spectra confirms that the major conformer in solution is (RRR)-Λ-(λλλλ), consistent with crystal structure analysis and DFT calculations. The magnetic susceptibility tensors for [Yb.L1] and [Yb.L2], obtained from a full pseudocontact chemical shift analysis, are very different, in agreement with a CASSCF calculation. The remarkably different pseudocontact shift behavior is explained by the change in the orientation of the pseudocontact shift field, as defined by the Euler angles of the susceptibility tensor.

Item Type:Article
Full text:(AM) Accepted Manuscript
Download PDF
(1061Kb)
Status:Peer-reviewed
Publisher Web site:https://doi.org/10.1021/acs.inorgchem.6b02291
Publisher statement:This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.6b02291.
Date accepted:02 March 2017
Date deposited:03 March 2017
Date of first online publication:15 March 2017
Date first made open access:15 March 2018

Save or Share this output

Export:
Export
Look up in GoogleScholar