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High pressure/low temperature polymorphism in 2,6-dimethylpyridine–formic acid cocrystals.

Lee, Rachael and Yufit, Dmitry S. and Probert, Michael R. and Steed, Jonathan W. (2017) 'High pressure/low temperature polymorphism in 2,6-dimethylpyridine–formic acid cocrystals.', Crystal growth & design., 17 (4). pp. 1647-1653.


Five new cocrystals of 2,6-dimethylpyridine (DMP) with formic acid (FA) were crystallized by application of pressure in a diamond anvil cell and by in situ cryo-crystallization. Mixtures in ratios 1:1, 1:2, and 1:3 of DMP–FA have crystallized via both methods. Both the 1:2 and 1:3 cocrystals exhibit high pressure/low temperature polymorphism.

Item Type:Article
Full text:(AM) Accepted Manuscript
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Publisher statement:This document is the Accepted Manuscript version of a Published Work that appeared in final form in Crystal Growth & Design, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see
Date accepted:28 February 2017
Date deposited:27 April 2017
Date of first online publication:01 March 2017
Date first made open access:01 March 2018

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