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Geometries of 11-vertex carborane monoanion radicals with 2n+3 skeletal electron counts

Patel, N.C.D.; Oliva-Enrich, J.M.; Fox, M.A.

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Authors

N.C.D. Patel

J.M. Oliva-Enrich



Abstract

While geometries of 12- and 13-vertex dicarbaborane (carborane) radicals with rare 2n+3 skeletal electrons have been determined elsewhere, the geometries of the 11-vertex dicarbaborane monoanion radicals with 2n+3 SE are established here for the first time by computations in agreement with observed electrochemical and electron paramagnetic resonance spectroscopy (EPR) data.

Citation

Patel, N., Oliva-Enrich, J., & Fox, M. (2017). Geometries of 11-vertex carborane monoanion radicals with 2n+3 skeletal electron counts. European Journal of Inorganic Chemistry, 2017(38-39), 4568-4574. https://doi.org/10.1002/ejic.201700419

Journal Article Type Article
Acceptance Date May 31, 2017
Online Publication Date Jul 5, 2017
Publication Date Jul 5, 2017
Deposit Date Jun 6, 2017
Publicly Available Date Mar 28, 2024
Journal European Journal of Inorganic Chemistry
Print ISSN 1434-1948
Electronic ISSN 1099-0682
Publisher Wiley-VCH Verlag
Peer Reviewed Peer Reviewed
Volume 2017
Issue 38-39
Pages 4568-4574
DOI https://doi.org/10.1002/ejic.201700419

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Copyright Statement
This is the peer reviewed version of the following article: Fox, Mark A., Patel, Natasha C. D. & Oliva-Enrich, Josep M. (2017). Geometries of 11-vertex carborane monoanion radicals with 2n+3 skeletal electron counts. European Journal of Inorganic Chemistry, which has been published in final form at https://doi.org/10.1002/ejic.201700419. This article may be used for non-commercial purposes in accordance With Wiley-VCH Terms and Conditions for self-archiving.




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