Tate, M. L. and Fuller, C. A. and Avdeev, M. and Brand, H. E. A. and McIntyre, G. J. and Radosavljevic Evans, I. (2017) 'Synthesis and characterisation of new Bi(iii)-containing apatite-type oxide ion conductors: the influence of lone pairs.', Dalton transactions., 46 (37). pp. 12494-12499.
Lone-pair cations are known to enhance oxide ion conductivity in fluorite- and Aurivillius-type materials. Among the apatite-type phases, the opposite trend is found for the more widely studied silicate oxide ion conductors, which exhibit a dramatic decrease in conductivity on Bi(III) incorporation. In this work, the influence of lone-pair cations on the properties of apatite-type germanate oxide ion conductors has been investigated by preparing and characterising seven related compositions with varying Bi(III) content, by X-ray and neutron powder diffraction and impedance spectroscopy. All materials are very good oxide ion conductors (with conductivities of up to 1.29 × 10−2 S cm−1 at 775 °C). Increasing Bi(III) content leads to increases in conductivity by up to an order of magnitude, suggesting significant differences in the oxide-ion conduction mechanisms between lone-pair-containing apatite-type germanate and silicate solid electrolytes.
|Full text:||(AM) Accepted Manuscript|
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|Publisher Web site:||https://doi.org/10.1039/C7DT02871G|
|Date accepted:||03 September 2017|
|Date deposited:||11 October 2017|
|Date of first online publication:||04 September 2017|
|Date first made open access:||04 September 2018|
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