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Monothiatruxene: a new versatile core for functional materials

Maciejczyk, Michal R.; Williams, J.A. Gareth; Robertson, Neil; Pietraszkiewicz, Marek

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Authors

Michal R. Maciejczyk

Neil Robertson

Marek Pietraszkiewicz



Abstract

A truxene molecule incorporating a sulfur atom at one of the three bridgehead positions has been prepared through an efficient route, together with its oxidized analogue (featuring an SO2 unit) and brominated derivatives. The photophysical, electrochemical and thermal properties of the compounds are presented: the materials show high thermal stability and the ability to form amorphous glasses. This central monothiatruxene core offers multiple routes to further modifications, thereby opening a way to the synthesis of a variety of novel functional materials beyond the parent truxene.

Citation

Maciejczyk, M. R., Williams, J. G., Robertson, N., & Pietraszkiewicz, M. (2017). Monothiatruxene: a new versatile core for functional materials. RSC Advances, 7(78), 49532-49535. https://doi.org/10.1039/c7ra07671a

Journal Article Type Article
Acceptance Date Oct 13, 2017
Online Publication Date Oct 25, 2017
Publication Date Oct 25, 2017
Deposit Date Oct 31, 2017
Publicly Available Date Mar 29, 2024
Journal RSC Advances
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 7
Issue 78
Pages 49532-49535
DOI https://doi.org/10.1039/c7ra07671a

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